Locally coordinated compounds (small coordination numbers)

cooElementalcoo-BBinarybonding
structurecrystalformulastructurecrystal
1lA14I2    molecular crystal
2nA8Se    polymeric crystal
3lA9graphite-C    covalent, semimetal
3nA7α-As3nAB α-GeTecovalent-ionic, semimetal
 A17black-P3nAB GeSecovalent-ionic
   2nA2B3 As2Se3covalent-ionic
4tA4diamond-C4tABB3 covalent-ionic
 hP4hexdia-C4tABB4 covalent-ionic
   2nAB2 SiO2covalent-ionic
6oAhα-Po6oAB β-GeTesemimetal
   4tAB2C2FeS2covalent-ionic