Phosphorus

Crystalline forms of the phosphorus (see phase diagram in [Clark10]):

3D   bcc >258GPa metal
  sc >10GPa
layered
(black-P)
  A7 >5GPa semimetal
black-P A17 stable phase semiconductor
polymeric
(red-P)
monoclinic-P mP84 Hittorf's-P widegap
semiconductor
    amorphous
molecular
(white-P)
α-P4 cI232* stable phase insulator
β-P4 aP24 <196K
γ-P4   <150K

* I-43m α-Mn structure, a=18.51, 58 molecules per unit cell

References