Carbon

Crystal structure of carbon allotropes
sp3 abc* diamond (A4) cF8 Fd-3m wide-gap semiconductor, metastable**
sp3 a hexagonal diamond (lonsdaleite) hP4 P63/mmc wurtzite form of diamond
sp2 ab graphite (hexagonal, A9) hP4 P63/mmc semimetal
  ab buckled hexagonal graphite hP4 P63mc deformation of graphite
  abc rhombohedral graphite hR2 R-3m deformation of smooth graphite sheets towards diamond
sp2 bct-4 tI8 I41/amd stacked trans-polyacetylene with CC bonds instead of CH
sp2 H-6 cP6 P6222 stacked trans-polyacetylene with CC bonds instead of CH
sp2 K4 cI8 I4132 Laves graph, unstable
sp2 C-20 cF80 Fm-3m another K4-type polymorph
sp3 M mC16 C2/m superhard monoclinic polymorph

* Stacking of virtual hexagonal layers
** See the phase diagram on Wikipedia

References