Bh, tungsten carbide

Structural typeBh
Common nametungsten carbide
Definition???
PrototypeWC
Pearson symbolhP2
Space group187 P-6m2 D3h1
Chemical formulaAX
Bonding???
Atomic positions  A (1a)   0    0    0   (marked by C)
 X (1d)  1/3  2/3  1/2  (marked by S)
CoordinationAX, XA – 6p
SublatticesA, X – sh (simple hexagonal, Af)
PDB filesBh
Parametersc/a≈1
Superstructurehcp for A=X and different c/a ratio
Substancestransition metals + IV (WC, MoC, AlSn), + V (WN, γ-NbN, MoP), +VI (TiS, NbS, TaS, ZrTe),
other compounds: IrB
AXac/a
WC2.9060.976
NbN2.9580.939
MoP3.2310.993
ZrTe3.7631.026