21 
thiopheneCOOMe2 molec-a optimized by CAM-B3LYPp2p, SG=2y
  S         0.00000000     1.46376360     0.00000000
  C         1.23012078     0.26586960     0.00299272
  C        -1.23012078     0.26586960    -0.00299272
  C         0.71911846    -0.99775140    -0.00511933
  C        -0.71911846    -0.99775140     0.00511933
  H         2.27779534     0.52991760    -0.01678533
  H        -2.27779534     0.52991760     0.01678533
  C        -1.64890421    -2.14828040     0.13013668
  O        -1.11985318    -3.15505640     0.83739005
  O        -2.78095213    -2.15117740    -0.29458340
  C        -1.97128597    -4.28889640     1.00486430
  H        -1.39562757    -5.00569440     1.58883721
  H        -2.88416409    -4.00743040     1.53373485
  H        -2.24123539    -4.71086240     0.03446623
  C         1.64890421    -2.14828040    -0.13013668
  O         1.11985318    -3.15505640    -0.83739005
  O         2.78095213    -2.15117740     0.29458340
  C         1.97128597    -4.28889640    -1.00486430
  H         1.39562757    -5.00569440    -1.58883721
  H         2.24123539    -4.71086240    -0.03446623
  H         2.88416409    -4.00743040    -1.53373485
